Kinetic and structural studies on 'tethered' Ru(II) arene ketone reduction catalysts.

نویسندگان

  • Fung Kei Kathy Cheung
  • Adam J Clarke
  • Guy J Clarkson
  • David J Fox
  • Mark A Graham
  • Changxue Lin
  • Adriana Lorente Crivillé
  • Martin Wills
چکیده

A series of kinetic and structural investigations on ruthenium-based catalysts for asymmetric transfer hydrogenation (ATH) of ketones are reported. A method is reported for monitoring the formation of ruthenium hydride species in real time using (1)H NMR spectroscopy.

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عنوان ژورنال:
  • Dalton transactions

دوره 39 5  شماره 

صفحات  -

تاریخ انتشار 2010